Chemistry - Thermodynamics - II Question with Solution | TestHub

ChemistryThermodynamics - IIFree Energy and EquilibriumMedium2 minPYQ_2015
ChemistryMediumsingle choice

The standard Gibbs energy change at 300 K for the reaction2AB+Cis 2494.2 J. At a given time, the composition of the reaction mixture isA=12, B=2andC=12. The reaction proceeds in the:[R=8.314 J/K-mol ,  e=2.718{Given antilog (-0.44)=0.36}

Options:

Answer:
C
Solution:

Δ G = - RT ln K C

2494.2 = - 8.314 × 300 ln K C

2494.2 = - 8.314 × 300 × 2.303 log K C

- 2494.2 2.303 × 300 × 8.314 = - 0.44 = log K C

log KC=-0.44

K C = 0.36

Q=[B][C][A]2=2×12122=4

Q>KC, reaction will shift in reverse direction.

Stream:JEESubject:ChemistryTopic:Thermodynamics - IISubtopic:Free Energy and Equilibrium
2mℹ️ Source: PYQ_2015

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