Chemistry - Thermodynamics - 1 Question with Solution | TestHub

ChemistryThermodynamics - 1Adiabatic Process/PolytropicEasy2 minPYQ_2020
ChemistryEasynumerical

The ratio Kp to Kc of a reaction is 24.63 L atm mol–1 at 27°C. If heat of reaction at constant pressure is 98.8 kcal, what is the heat of reaction (in kcal)  at constant volume?

Answer:
98.20
Solution:

KpKc=RTΔng

 

RTΔng=24.63 Latmmol-1

0.0821 × 3 0 0 Δ n g = 24.63

Δ n g = 1

Δ H = Δ E + Δ n g RT

Δ E = Δ H - RT = 98.8 - 2 × 1 0 - 3 × 3 0 0 = 98.2 kcal

Stream:NTA_ABHYASSubject:ChemistryTopic:Thermodynamics - 1Subtopic:Adiabatic Process/Polytropic
2mℹ️ Source: PYQ_2020

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