Chemistry - Stoichiometry Question with Solution | TestHub

ChemistryStoichiometryProblems Based on Mixtures, Percentage PurityMedium2 minQB
ChemistryMediumsingle choice
Passage / Comprehension

Chile saltpeter, a source of NaNO₃, also contains NaIO₃. The NaIO₃ can be used as a source of iodine, produced in the following reactions: IO₃⁻ + 3HSO₃⁻ I⁻ + 3H⁺ + 3SO₄²⁻ and 5I⁻ + IO₃⁻ + 6H⁺ 3I₂ + 3H₂O. One litre of Chile saltpeter solution containing 5.94 g NaIO₃ is treated with stoichiometric quantity of NaHSO₃. Now an additional amount of same solution is added to the reaction mixture to bring about the second reaction. (I = 127)

How many grams of NaHSO₃ is required in step I, for complete reaction?

Options:

Answer:
A
Solution:

NaIO₃ = 5.94/198 = 0.03 mol. Step I needs 3 mol HSO₃⁻ per mol IO₃⁻, so NaHSO₃ = 0.09 mol. Mass = 0.09 × 104 = 9.36 g, matching (a).

Stream:JEESubject:ChemistryTopic:StoichiometrySubtopic:Problems Based on Mixtures, Percentage Purity
⏱ 2mℹ️ Source: QB

Doubts & Discussion

Loading discussions...