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Chemistry - Liquid Solution Question with Solution | TestHub

ChemistryLiquid SolutionAbnormal Colligatiove PropertiesHard2 minPYQ_2021
ChemistryHardnumerical

1.22 gof an organic acid is separately dissolved in100 gof benzeneKb=2.6 K kg mol-1and100 gof acetoneKb=1.7 K kg mol-1.The acid is known to dimerize in benzene but remain as a monomer in acetone. The boiling point of the solution in acetone increases by0.17°C.The increase in boiling point of solution in benzene inCisx×10-2.The value ofxis (Nearest integer)
[Atomic mass :C=12.0, H=1.0, O=16.0]

Answer:
13.00
Solution:

ΔTb=i×kb×molality ;m=w1GMM1×1000w2
For Acetone solution
0.17=1×1.7×1.22GMM×1000100
GMM of substance=122 gm/mol
For Benzene solution
ΔTb=i×kb×m=12×2.6×1.22122×1000100=0.13=13×10-2
=13

Stream:JEESubject:ChemistryTopic:Liquid SolutionSubtopic:Abnormal Colligatiove Properties
2mℹ️ Source: PYQ_2021

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