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ChemistryLiquid SolutionAzeotropic Mixtures/Non-ideal solution.Medium2 minPYQ_2020
ChemistryMediumsingle choice

At35 oC,the vapour pressure ofCS2,is512mmHg and that of acetone is144 mmHg.A solution ofCS2in acetone has a total vapour pressure of600 mmHg. The false statement amongst the following is:

Options:

Answer:
B
Solution:

P observed =600

P Cal = P A 0 x A +P B 0 x B

=512x+344344x

=168x+344

=512 (If x=1 for maximum value)

Thus, P cal < P observed

Thus' the process is deviated from Raoult's law, showing positive deviation from Raoult's law.

ΔH>0 ,i.e., is absorbed

Stream:JEESubject:ChemistryTopic:Liquid SolutionSubtopic:Azeotropic Mixtures/Non-ideal solution.
2mℹ️ Source: PYQ_2020

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