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ChemistryLiquid SolutionRaoult's LawMedium2 minPYQ_2015
ChemistryMediumsingle choice

The vapour pressure of acetone at20oCis185 torr. When1.2 gof a non-volatile substance was dissolved in100 gof acetone at20oC, its vapour pressure was183 torr. The molar mass(g mol-1)of the substance is:

Options:

Answer:
C
Solution:

Δ P = 1 8 5 - 1 8 3 = 2 torr

MCH3-CO||-CH3=15×2+16+12=58 g/mol

ΔPP0=185-183185=2185=XB=1.2M1.2M+10058

1.2 M << 1 0 0 5 8

⇒   2 1 8 5 = 1.2 M × 5 8 1 0 0

M = 5 8 × 1.2 1 0 0 × 1 8 5 2

=64.3864 g/mol

Stream:JEESubject:ChemistryTopic:Liquid SolutionSubtopic:Raoult's Law
2mℹ️ Source: PYQ_2015

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