Chemistry - Coordination Chemistry Question with Solution | TestHub

ChemistryCoordination ChemistryWerner theory + calculation of EANMedium2 minQB
ChemistryMediumsingle choice

(A)

(B)

(C)

A, B, C cannot be distinguished by

Options:

Answer:
C
Solution:

The complexes A, B, and C differ in the number of ionizable Cl⁻ ions outside the coordination sphere (3, 2, and 1 respectively). Hence, they can be distinguished by electrical conductivity and by quantitative precipitation with AgNO₃, as different amounts of AgCl are formed. They can also be distinguished by weight loss with concentrated H₂SO₄ because they contain different numbers of water molecules. However, BaCl₂ does not give any characteristic difference, since chloride ions do not form an insoluble precipitate with Ba²⁺.

Answer: (c) BaCl₂ solution

Stream:JEESubject:ChemistryTopic:Coordination ChemistrySubtopic:Werner theory + calculation of EAN
2mℹ️ Source: QB

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