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Chemistry - Coordination Chemistry Question with Solution | TestHub

ChemistryCoordination ChemistryIsomerismMedium2 minPYQ_2019
ChemistryMediumsingle choice

A reaction of cobalt(III)chloride and ethylenediamine in a1 : 2mole ratio generates two isomeric productsA(violet-coloured) andB(green-coloured).Acan show optical activity, but,Bis optically inactive. What type of isomers doAandBrepresent?

Question diagram: A reaction of cobalt ( III ) chloride and ethylenediamine in

Options:

Answer:
D
Solution:

The coordination number of cobalt is 6.

The mole ratio of CoCl3 and en is 1 : 2.

Hence,

CoCl3+2 enCoen2Cl2 Cl

The complex formed shows geometrical isomerism.

The complex exists as cis and trans isomers among which the trans isomer is optically inactive.

 

Stream:JEESubject:ChemistryTopic:Coordination ChemistrySubtopic:Isomerism
2mℹ️ Source: PYQ_2019

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