Chemistry - Thermodynamics - II Question with Solution | TestHub
Supercooled rain water strikes the wind screen of a car and converts to ice in winter season. With reference to second law of thermodynamics which statement is correct for above process.
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Solution:
At , liquid water is supercooled and freezes spontaneously to form ice. During freezing, the entropy of the system decreases because ice is more ordered than liquid water. However, freezing is an exothermic process, so heat is released to the surroundings, causing the entropy of the surroundings to increase. According to the second law of thermodynamics, for a spontaneous process, . Therefore, the increase in entropy of the surroundings is greater than the decrease in entropy of the system.