Chemistry - Thermodynamics - I Question with Solution | TestHub

ChemistryThermodynamics - IFirst law of ThermodynamicsHard2 minQB
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A thermodynamic process is shown in the following figure. The pressure and volumes corresponding to some points in the figure are: PA = 2 × 105 Pa, PB = 5 × 105 Pa, VA = 1 × 10-3 m3, VD = 4 × 10-3 m3. In the process AD, 1000 J of heat is added to the system and in DC, 750 J of heat is added. The heat absorbed by the system in the direct process AC (along the straight line) would be

figure

Options:

Answer:
A
Solution:

AD is at constant pressure PA: WAD = 2 × 105 × 3 × 10-3 = 600 J, so Δ UAD = 1000 - 600 = 400 J. DC is at constant volume: W = 0, Δ UDC = 750 J. Δ UAC = 1150 J (state function). Along the straight line AC, work = trapezoid area = ((2+5) × 105)/2 × 3 × 10-3 = 1050 J. QAC = Δ U + W = 1150 + 1050 = 2200 J. Matches (a).

Stream:JEESubject:ChemistryTopic:Thermodynamics - ISubtopic:First law of Thermodynamics
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