Chemistry - Thermodynamics - I Question with Solution | TestHub

ChemistryThermodynamics - IAdiabatic Process/PolytropicMedium2 minQB
ChemistryMediumsingle choice
Passage / Comprehension

The adiabatic compression of a mixture of 3 volumes of hydrogen and 1 volume of oxygen from 640 ml to 20 ml caused explosion. The initial pressure and temperature of the gaseous mixture were 2 atm and 127°C.

What is the magnitude of maximum work performed by the gaseous mixture before explosion?

Options:

Answer:
C
Solution:

n = PV/RT = (2 × 0.640)/(0.0821 × 400) ≈ 0.039 mol. Adiabatic, q = 0: |w| = |ΔU| = n·Cv·ΔT = 0.039 × (5/2 × 8.314) × (1600 − 400) ≈ 0.039 × 20.785 × 1200 ≈ 972 J. Matches (c).

Stream:JEESubject:ChemistryTopic:Thermodynamics - ISubtopic:Adiabatic Process/Polytropic
⏱ 2mℹ️ Source: QB

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