Chemistry - Thermodynamics - I Question with Solution | TestHub

ChemistryThermodynamics - IIsothermal Process/Isobaric/IsochoricEasy2 minQB
ChemistryEasysingle choice

Two moles of an ideal gas are contained under a weightless piston of a vertical cylinder at a temperature T. The space over the piston opens into the atmosphere. What work has to be performed in order to increase isothermally the gas volume under the piston k times by slowly raising the piston? The friction of the piston against the cylinder walls is negligibly small.

Options:

Answer:
C
Solution:

The weightless piston means the initial gas pressure equals Patm, so PatmV1 = 2RT. Work by the agent = ∫(Patm - Pgas)dV = Patm(k-1)V1 - 2RTln k = 2RT(k - 1) - 2RTln k = 2RT(k - 1 - ln k). Matches (c).

Stream:JEESubject:ChemistryTopic:Thermodynamics - ISubtopic:Isothermal Process/Isobaric/Isochoric
⏱ 2mℹ️ Source: QB

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