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Chemistry - Thermodynamics - I Question with Solution | TestHub

ChemistryThermodynamics - IFirst law of ThermodynamicsMedium2 minPYQ_2020
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The heat of combustion of ethanol into carbon dioxides and water is-327Kcal at constant pressure. The heat evolved (in cal) at constant volume at27° C(if all gases behave ideally) isR=2 calmol-1K-1________

Answer:
326400
Solution:

C2H5OH()+O2(g)2O2(g)+3H2O();ΔHC=-327Kcal
ΔHc=ΔUC+ΔngRT
-327×103=ΔUC+1×2×300
ΔUC=-326400 cal

So heat evolved as constant volume is 326400cal 

Stream:JEESubject:ChemistryTopic:Thermodynamics - ISubtopic:First law of Thermodynamics
2mℹ️ Source: PYQ_2020

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