Chemistry - Thermochemistry Question with Solution | TestHub
Statement 1: The magnitude of enthalpy of combustion of 2-Butene is less than that of 1-Butene.
Statement 2: 2-Butene is thermodynamically more stable than 1-Butene.
Options:
Answer:
Solution:
2-Butene is a more substituted and thus more stable alkene than 1-Butene (Statement 2 is correct). Both isomers combust to produce the same products, 4CO2 + 4H2O. Consequently, the more stable 2-butene begins at a lower enthalpy and releases less heat upon combustion. This means that the absolute value of the enthalpy of combustion for 2-butene is less than that for 1-butene: |Δc H(2-butene)| < |Δc H(1-butene)| (Statement 1 is correct). Statement 2 provides the precise explanation for this observation. The answer is (a).
