Chemistry - Thermochemistry Question with Solution | TestHub

ChemistryThermochemistryAdiabatic Process/PolytropicMedium2 minPYQ_2020
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If enthalpy of hydrogenation of C 6 H 6 l into C 6 H 12 l is205 kJand resonance energy of C 6 H 6 l is152 kJ mol1then enthalpy of hydrogenation of l to C 6 H 12 l is?
[Assume enthalpiies of vapourisation of all liquids involved are equal].

Options:

Answer:
D
Solution:

C 6 H 6 l + 3 H 2 g C 6 H 1 2 l
Δ H hyd C 6 H 6 l = - 2 0 5  kJ
Benzene on reactant side so add resonance energy of benzene with sign. Heat evolved for hydrogenation of three double bonds
=205152=357 kJ mol 1
Δ H hyd = - 3 5 7 3 = - 1 1 9  kJ / mole

Stream:NTA_ABHYASSubject:ChemistryTopic:ThermochemistrySubtopic:Adiabatic Process/Polytropic
2mℹ️ Source: PYQ_2020

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