Chemistry - Thermochemistry Question with Solution | TestHub

ChemistryThermochemistryAdiabatic Process/PolytropicMedium2 minPYQ_2020
ChemistryMediumsingle choice

The enthalpy of neutralisation of NH4OH and CH3COOH is -10.5 kcal mol-1​ and enthalpy of neutralisation of CH3COOH with strong base is -12.5 kcal mol-1.The enthalpy of ionisation of NH4OH will be

Options:

Answer:
C
Solution:

Δ H⁡ neutr. for strong acid with strong base = - 1 3 · 7 kcal equiv -1

Enthalpy of ionisation of acetic acid & NH4OH together

=−10.5−( −13.7 )=+3 .2 kcal mol -1

Enthalpy of ionisation of only acetic acid

=−12.5−( −13.7 )=+1 .2 kcal mol -1

Enthalpy of ionisation of only NH4OH

=3.2−1.2= 2 kcal mol -1

Stream:NTA_ABHYASSubject:ChemistryTopic:ThermochemistrySubtopic:Adiabatic Process/Polytropic
⏱ 2mℹ️ Source: PYQ_2020

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