Chemistry - STEREO ISOMERISM Question with Solution | TestHub
Identify chiral and achiral molecules in each of the following pair of compounds. (Wedge and Dash representations).
(I) (i)
(ii) 
(II) (i)
(ii) 
(III) (i)
(ii) CH3CH2CH2CH2Br
Options:
Answer:
Solution:
Ans. (A) (I) (i) chiral, (ii) achiral; (II) (i) chiral, (ii) achiral; (III) (i) chiral, (ii) achiral.
Sol. (I) (i) The carbon bears four different groups (H, OH, Br, CH3) : chiral. (ii) Two identical Br atoms on the same carbon : achiral.
(II) (i) Pentan-2-ol: the carbinol carbon bears H, OH, CH3 and n-propyl : chiral. (ii) Pentan-3-ol: two identical ethyl groups on the carbinol carbon : achiral.
(III) (i) 2-Bromobutane: the C-2 bears H, Br, CH3 and C2H5 : chiral. (ii) 1-Bromobutane has no stereocentre : achiral.
