Chemistry - STEREO ISOMERISM Question with Solution | TestHub

ChemistrySTEREO ISOMERISMOPTICAL PURITY/ENANTIOMERIC EXCESS, POLARIMETER TUBE EXPERIMENTMedium2 minQB
ChemistryMediumsingle choice

Assertion :- D-Glucose and L-Glucose are enantiomers of each other.

Reason :- L-glucose has –OH group at last chiral carbon (according to IUPAC numbering) on left side.

Options:

Answer:
B
Solution:

Question Explanation:

This question tests the relationship between D-Glucose and L-Glucose and examines how the D/L

configuration of sugars is determined.

Concept :

This question is based on Enantiomers, D–L configuration, Chiral carbon, Fischer projection of

Biomolecules.

Solution : D-Glucose and L-Glucose are non-superimposable mirror images, making them enantiomers.

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so the assertion is correct.

L-glucose has –OH group at the last chiral carbon (according to IUPAC numbering) on the left side →

True

In Fischer projection, the D/L notation is determined by the position of the –OH group on the last chiral

carbon (penultimate carbon).

OH on the right → D-form

OH on the left → L-form

Since the Reason correctly describes the structural criterion for identifying the L-form, but it is not the

explanation of the Assertion.

Final Answer: Option (B)

Stream:JEESubject:ChemistryTopic:STEREO ISOMERISMSubtopic:OPTICAL PURITY/ENANTIOMERIC EXCESS, POLARIMETER TUBE EXPERIMENT
2mℹ️ Source: QB

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