Chemistry - Salt Analysis Question with Solution | TestHub

ChemistrySalt AnalysisTEST OF CATIONS, Group 3, 4, 5, 6, 0Medium2 minQB
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From the aqueous solution of 'A' on sequential tests of group analysis for cations, reddish brown ppt is observed with group-III reagent :

Find the oxidation state of metal present in salt "A"

Options:

Answer:
D
Solution:

The group-III reagent for cation analysis typically involves NH₄Cl and NH₄OH. A reddish-brown precipitate (ppt) is characteristic of Fe³⁺ ions, which form Fe(OH)₃. Therefore, the metal in salt "A" is likely iron in the +3 oxidation state.

 

However, the question asks for the oxidation state of "metal present in salt 'A'", not specifically the cation that precipitates. If "A" is a complex salt or contains other metals, the oxidation state of the *specific* metal forming the reddish-brown ppt is +3, but the overall oxidation state of *all* metals in "A" cannot be confirmed without more information. Therefore, it cannot be predicted in a confirmed manner.

 

Final Answer is D.

Stream:JEESubject:ChemistryTopic:Salt AnalysisSubtopic:TEST OF CATIONS, Group 3, 4, 5, 6, 0
2mℹ️ Source: QB

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