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ChemistrySalt AnalysisMiscellaneous/MixedHard2 minPYQ_2015
ChemistryHardmatching list

An aqueous solution of a salt X turns blood red on treatment withSCN-and blue on treatment withK4FeCN6, X also gives a positive chromyl chloride test. The salt X is:

Options:

Answer:
A
Solution:

FeCl 3 + 3 SCN aq - Fe SCN 3 + 3 Cl - Blood red

4 FeCl 3 + 3 K 4 Fe CN 6 1 2 KCl + Fe 4 Fe CN 6 Prussian blue

2 FeCl 3 + 3 H 2 SO 4 Fe 2 SO 4 3 + 6 HCl

K 2 Cr 2 O 7 + 2 H 2 SO 4 2 KHSO 4 + 2 CrO 3 + H 2 O

CrO 3 + 2 HCl CrO 2 Cl 2 + H 2 O Chromyl chloride

CrO 2 Cl 2 +4NaOH Na 2 CrO 4 Yellow +2NaCl+2H 2 O

Na 2 CrO 4 + Pb CH 3 COO 2 PbCrO 4 + 2 CH 3 COONa Yellow ppt.

Stream:JEESubject:ChemistryTopic:Salt AnalysisSubtopic:Miscellaneous/Mixed
2mℹ️ Source: PYQ_2015

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