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Chemistry - Redox Reactions Question with Solution | TestHub

ChemistryRedox ReactionsTitrationMedium2 minPYQ_2021
ChemistryMediumnumerical

A sample containing iron is completely dissolved in cold dilute to prepare a of solution. Titration of of this solution requires of solution to reach the end point. Number of moles of present in solution is (consider complete dissolution of ). The amount of iron present in the sample is by weight.
(Assume: reacts only with in the solution Use: Molar mass of iron as )
The value ofyis________ .

Answer:
18.75
Solution:

Moles of Fe2+ present in 250 ml solution =x×10-2

Moles of Fe2+ present in 25 ml solution = x×10-3 mole

At equivalence point

eq. of Fe2+ = eq. of KMnO4

MolesFe2+×vfFe2+=MolesKMnO4×vfKMnO4

x×103×1=0.03×12.5×103×5

x=1.875 mole

Moles of Fe2+ present in 250 ml solution =1.875×10-2

Mass of Fe2+ present in 250 ml solution

=1.875×10-2×56 gm

=1.05 gm

% of Fey=1.055.6×100

=18.75%

Stream:JEE_ADVSubject:ChemistryTopic:Redox ReactionsSubtopic:Titration
2mℹ️ Source: PYQ_2021

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