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ChemistryLiquid SolutionColligative PropertiesHard2 minPYQ_2022
ChemistryHardnumerical

A solution containing2.5×10-3 kgof a solute dissolved in75×10-3 kgof water boils at373.535 K. The molar mass of the solute ismol-1·[nearest integer] (Given :KbH2O=0.52 K kg mol-1and boiling point of water=373.15 K)

Answer:
45.00
Solution:

ΔTb=iKbm

ΔTb=Elevation of boiling pointKb= molal boiling point elevation constantm=molalityi=van't hoff factor

m=2.5M×100075

Tb=Tb-TboTb=Boiling point of the solutionTbo=Boiling point of the solventTb=373.535-373.15        =0.385 K

ΔTb=iKbm

0.385=1×0.52×2.5×1000M×75

The molar mass of the solute,M=45 g/ml.

Stream:JEESubject:ChemistryTopic:Liquid SolutionSubtopic:Colligative Properties
2mℹ️ Source: PYQ_2022

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