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ChemistryLiquid SolutionAbnormal Colligatiove PropertiesMedium2 minPYQ_2019
ChemistryMediumsingle choice

Molecules of benzoic acidC6H5COOHdimerise in30gof benzene. 'w'gof benzoic acid shows a depression in freezing point equal toK. If the percentage association of the acid to form dimer in the solution is80, thenwis:(Given thatKf=5 Kmol-1, molar mass of benzoic acid=122 gmol-1)

Options:

Answer:
B
Solution:

ΔTf =kf×m×i(i)

Molecular weight ofC6H5COOH=112

n = 2  because benzoic acid is dimerised, β = 80 % = 0.8

Herei=1n-1β+1

i=12-1 0.8+1

=0.6

Put the value in equation(i)

2=0.6×wt.of benzoic acid112301000×5

weight  of benzoic acid=2.4 g

Stream:JEESubject:ChemistryTopic:Liquid SolutionSubtopic:Abnormal Colligatiove Properties
2mℹ️ Source: PYQ_2019

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