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Chemistry - Ionic Equilibrium Question with Solution | TestHub

ChemistryIonic EquilibriumpH of Strong and Weak Acids and BasesHard2 minPYQ_2019
ChemistryHardstatement

Consider the following statements
(a)The pH of a mixture containing400 mLof0.1 M H2SO4and400 mLof0.1 M NaOHwill be approximately1.3.
(b)Ionic product of water is temperature dependent.
(c)A monobasic acid withKa=10-5has apH=5. The degree of dissociation of this acid is50%.
(d)The Le Chatelier's principle is not applicable to common-ion effect.
The correct statements are:

Options:

Answer:
D
Solution:

Strong acid + Strong base mixture
n H2SO4>n[NaOH]SoH+will be more
H+=2×0.1×400-0.1×400800=0.05
pH=-logH+=-log0.05=1.3
(b) The ionic product of water is temperature dependent
(c)HCOOHH++HCOO-(weak acid)
ka=Cα21-α
ka=Cα.α1-α
ka=H+α1-α
10-5=10-5×α1-α
1-α=α
α=12=0.5
(d) Le-Chatelier’s Principle in applicable on Common Ion Effect

Stream:JEESubject:ChemistryTopic:Ionic EquilibriumSubtopic:pH of Strong and Weak Acids and Bases
2mℹ️ Source: PYQ_2019

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