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Chemistry - Ionic Equilibrium Question with Solution | TestHub

ChemistryIonic EquilibriumpH of Strong and Weak Acids and BasesMedium2 minPYQ_2015
ChemistryMediumsingle choice
Passage / Comprehension

When 100 mL of 1.0 M HCl was mixed with 100 mL of 1.0 M NaOH in an insulated beaker at constant pressure, a temperature increase of5.7oCwas measured for the beaker and its contents (Expt.1). Because the enthalpy of neutralization of a strong acid with a strong base is a constant(-57.0 kJ mol-1), this experiment could be used to measure the calorimeter constant. In a second experiment (Expt. 2), 100 mL of 2.0 M acetic acid(Ka=2.0×10-5)was mixed with 100 mL of 1.0 M NaOH (under identical conditions to Expt. 1) where a temperature rise of5.6oCwas measured. (Consider heat capacity of all solutions as4.2 J g-1 K-1and density of all solutions as1.0 g mL-1)

The pH of the solution after Expt. 2 is

Options:

Answer:
B
Solution:

Final solution contain 0.1 mole ofCH3COOHandCH3COONaeach.
Hence it is a buffer solution.
pH=pKa+log[CH3COO-][CH3COOH]
=5-log2+log0.10.1=4.7

Stream:JEE_ADVSubject:ChemistryTopic:Ionic EquilibriumSubtopic:pH of Strong and Weak Acids and Bases
2mℹ️ Source: PYQ_2015

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