Chemistry - Ideal Gas Question with Solution | TestHub
A treasure hunter gets trapped inside an old sealed chamber whose stale air contains 8.0% CO (by volume), along with O₂ and N₂. The safe limit of CO is less than 0.0005% by volume. His partner outside cannot enter, so he pushes air out of the chamber through a narrow vent with a hand bellows: each stroke draws out three-fourths of the air present in the chamber, and fresh air then seeps back in until the pressure is again 1 atm. How many strokes does he need so that the chamber air becomes safe?
Answer:
Solution:
Each stroke removes of the air, and fresh CO-free air restores the pressure. Therefore, the CO mole fraction is multiplied by per stroke. The concentration after strokes, , can be expressed as:
For a safe condition, the CO concentration must be less than .
This inequality can be rewritten as:
To find the minimum number of strokes, , we evaluate powers of 4:
Since and , he needs strokes. After 7 strokes, the concentration will be:
