Chemistry - Ideal Gas Question with Solution | TestHub

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Passage / Comprehension

Chemical explosions are characterised by the instantaneous release of large quantities of hot gases, which set up a shock wave of enormous pressure and velocity. Explosion of a compound X releases four gases A, B, C and D.

n X a A(g) + b B(g) + c C(g) + d D(g)

Assume that the explosion of 1 mol of X releases gases with a temperature of 2727°C and a volume of 3.0 l at 410 atm pressure. (R = 0.0821 l-atm/K-mol)

When gases B, C and D were passed through a tube of powdered Li₂O, gas B reacted to form Li₂CO₃. The remaining gases C and D were collected in another 821 ml flask at a pressure of 0.6 atm at 27°C. How many moles of B were present and what is its likely identity?

Options:

Answer:
D
Solution:

n(C+D) = 0.6 × 0.821/(0.0821 × 300) = 0.02 mol. n(B) = 0.06 - 0.02 = 0.04 mol; formation of Li₂CO₃ with Li₂O identifies B as CO₂. Hence (d).

Stream:JEESubject:ChemistryTopic:Ideal GasSubtopic:Problems related with container/piston/SPM
⏱ 2mℹ️ Source: QB

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