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ChemistryHalogen DerivativeNUCLEOPHILIC SUBSTITUTION REACTIONS (SN1 AND SN2), SN(NEIGHBOURING GROUP PARTICIPATION), SNIHard2 minPYQ_2023
ChemistryHardsingle choice

2-Methyl propyl bromide reacts with C2H5O-and gives A whereas on reaction with C2H5OH it gives B. The mechanism followed in these reactions and the products A and B respectively are:

Question diagram: 2 - Methyl propyl bromide reacts with C 2 H 5 O - and gives

Options:

Answer:
A
Solution:

The reaction between methyl propyl bromide and C2H5O- proceeds via an SN2 (substitution nucleophilic bimolecular) mechanism. In this mechanism, the nucleophile attacks the carbon atom bearing the bromine (the electrophilic carbon) in a single step, leading to the displacement of the bromine atom.

The reaction between methyl propyl bromide and C2H5OH can proceed via either an SN1 (substitution nucleophilic unimolecular). Here C2H5OH is a weak nucleophile. During the reaction 1,2-hydrogen shift will occur and tert-butyl ethyl ether is formed.

Stream:JEESubject:ChemistryTopic:Halogen DerivativeSubtopic:NUCLEOPHILIC SUBSTITUTION REACTIONS (SN1 AND SN2), SN(NEIGHBOURING GROUP PARTICIPATION), SNI
2mℹ️ Source: PYQ_2023

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