Chemistry - GOC Question with Solution | TestHub

ChemistryGOCAcid BaseEasy2 minQB
ChemistryEasysingle choice

Which of the following indicated H-atom is most acidic in nature?

structure

Options:

Answer:
A
Solution:

Removing Ha gives a carbanion allylic to the central C=C bond, and that double bond is conjugated with both carbonyl groups : the charge delocalises through the diene system onto BOTH carbonyl oxygens (a vinylogous enolate with four resonance structures). Hb and Hc are ordinary α protons whose anions delocalise over only one carbonyl, and Hd is a plain beta C-H with no resonance stabilisation at all. The most stabilised conjugate base comes from Ha, so Ha is the most acidic.

Stream:JEESubject:ChemistryTopic:GOCSubtopic:Acid Base
⏱ 2mℹ️ Source: QB

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