Chemistry - Electrochemistry Question with Solution | TestHub

ChemistryElectrochemistryMiscellaneous/MixedEasy2 minPYQ_2020
ChemistryEasynumerical

The standard EMF. of a cell, involving one electron change is found to be 0.591 V at25. The equilibrium constant of the reaction is 10 x . Find the value of x .
F = 96500 C  equivalent-1 , R = 8.314 J K -1  mol -1

Answer:
10.00
Solution:

ΔG=ΔG°0.591nlogQ

at equilibrium

ΔG=0,Ecell=0,Q=KC,ΔG°=0.5911logQ

E  cell = E  cell o 0.0591 n log K c

0 = 0.591 0.0591 1   log K c

  0.591 = 0.0591  log K c

⇒    log Kc = 0.5910.0591 = 10

∴      K c  =  antilog 10  =  1 × 10 10 .

Stream:NTA_ABHYASSubject:ChemistryTopic:ElectrochemistrySubtopic:Miscellaneous/Mixed
2mℹ️ Source: PYQ_2020

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