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ChemistryElectrochemistryGalvanic cells/Nernst Equation/Concentration CellsHard2 minPYQ_2019
ChemistryHardsingle choice

In the electrolysis of aqueous sodium chloride with inert electrodes the products obtained at anode and cathode respectively are

Options:

Answer:
C
Solution:

In the electrolysis of aqueous sodium chloride with inert electrodes, the products obtained at anode and cathode respectively areCl2andH2.
The solution contains four ionsNa+,Cl-,H+,OH.
Following reaction takes place:
At cathode
Na+aq+e-→Nas;                              ENa+/Na-=-2.71V2H2Ol+2e-→H2g+2O-Haq;                                        EH2O/H2o=-0.83V
At anode
2Cl-aq→Cl2g+2e-;ECl-/Cl2o=-1.36V2H2O2l→Og+4H+aq+4e-;                                                                  EH2O/O2o=-1.23 V
EH2O/H2o>ENa+/Nao.is formed at cathode.
WhereasEH2O/O2o>ECl-/Cl2o.So, formed at anode.

Stream:MHT_CETSubject:ChemistryTopic:ElectrochemistrySubtopic:Galvanic cells/Nernst Equation/Concentration Cells
⏱ 2mℹ️ Source: PYQ_2019

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