Chemistry - Coordination Chemistry Question with Solution | TestHub

ChemistryCoordination ChemistrySynergic bondingMedium2 minQB
ChemistryMediummultiple choice

Consider the following reaction

image.png

Which of the following statement is incorrect regarding the above reaction?

Options:(select one or more)

Answer:
A, C
Solution:

Statement A is incorrect because carbon monoxide (CO) is a monohapto () ligand that binds through a single carbon atom, meaning both complexes do not consist exclusively of trihapto () ligands.

 

Statement C is incorrect because a standard terminal carbonyl (CO) ligand always acts as a 2-electron donor via its carbon lone pair, not a 3-electron donor.

 

Statement B is correct as the transformation involves a change in oxidation states or electron count, making it a classic organometallic redox reaction.

 

Statement D is correct because transition metal carbonyl complexes inherently involve synergic bonding through -donation and -backdonation.

Stream:JEESubject:ChemistryTopic:Coordination ChemistrySubtopic:Synergic bonding
⏱ 2mℹ️ Source: QB

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