Chemistry - Coordination Chemistry Question with Solution | TestHub

ChemistryCoordination ChemistryIntroduction, About ligandMedium2 minQB
ChemistryMediumnumerical
Passage / Comprehension

Species which donate electron pair to central atom are called ligands and number of electron pair donated by ligand is called denticity.

Ligands which contains more than one type of donor atoms are called ambidentate ligands.

Find the total number of ligands which are monodentate as well as ambidentate?

CN⁻, NO₂⁻, OCN⁻, C₂O₄²⁻, dmg⁻¹, SCN⁻¹, C₂O₂S₂²⁻

Answer:
4.00
Solution:

To be monodentate, a ligand binds through one donor atom. To be ambidentate, it can bind through two different donor atoms.

From the given list, the ligands that are both monodentate and ambidentate are:

CN⁻ (binds via C or N)

NO₂⁻ (binds via N or O)

OCN⁻ (binds via N or O)

SCN⁻ (binds via S or N)

Thus, there are 4 such ligands.

Stream:JEESubject:ChemistryTopic:Coordination ChemistrySubtopic:Introduction, About ligand
⏱ 2mℹ️ Source: QB

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