Chemistry - Coordination Chemistry Question with Solution | TestHub

ChemistryCoordination ChemistryIntroduction, About ligandMedium2 minQB
ChemistryMediumsingle choice
Passage / Comprehension

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Which of the following complex having -acid ligand(s) :-

Options:

Answer:
A
Solution:

A π-acid ligand accepts electron density from the metal through back-bonding.

 

* Ferrocene (C₅H₅⁻): Cp ligand has vacant π* orbitals → π-interaction possible.

* Potassium ferrocyanide (CN⁻): CN⁻ is a strong π-acceptor ligand.

* Sodium nitroprusside (CN⁻, NO⁺): both CN⁻ and NO⁺ are π-acid ligands.

* Zeise's salt contains ethylene (C₂H₄), a classic π-acid ligand.

 

Stream:JEESubject:ChemistryTopic:Coordination ChemistrySubtopic:Introduction, About ligand
2mℹ️ Source: QB

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