Chemistry - Coordination Chemistry Question with Solution | TestHub

Statement 1 : Among ${\mathrm{MnCl}}_4^{2-},{\mathrm{NO}}_2$ monomer, ${\mathrm{O}}_2^{-},{\mathrm{Mn}}_3{\mathrm{O}}_4,{\mathrm{CuCl}}_4^{2-},{\mathrm{K}}_2{\mathrm{MnO}}_4$ only 5 species are paramagnetic.

Statement 2 : Among ${\left[\mathrm{Pt}\left({\mathrm{C}}_2{\mathrm{H}}_4\right){\mathrm{Cl}}_3\right]}^{-},\left[\mathrm{Ir}(\mathrm{CO})\mathrm{Cl}{\left({\mathrm{PPh}}_3\right)}_2\right],\left[\mathrm{Pt}{\left({\mathrm{PPh}}_3\right)}_3\right],\mathrm{Fe}(\mathrm{CO}{)}_5,{\left[\mathrm{Ag}{\left({\mathrm{NH}}_3\right)}_2\right]}^{+}$, $\left[\mathrm{Co}(\mathrm{CO}{)}_3\mathrm{NO}\right],\mathrm{Ti}{\left({\eta }^1-{\mathrm{C}}_5{\mathrm{H}}_5\right)}_2{\left({\eta }^5-{\mathrm{C}}_5{\mathrm{H}}_5\right)}_2$ only in 5 complexes central metal have 16 electron in their valence shell.