Chemistry - Coordination Chemistry Question with Solution | TestHub
For each of the following coordination complexes, match the given compound with the correct number of coordinate bonds (or chelate rings, as specified). Identify all correct matches.
Options:(select one or more)
Answer:
Solution:
(A) is correct: The complex contains three peripheral Co atoms, each coordinated by 4 NH₃ ligands, giving a total of Co-N bonds.
(B) is correct: Each of the two Co atoms has 4 NH₃ ligands (8 bonds), and the bridging -NH₂ group adds 2 more Co-N bonds, totaling 10.
(C) is incorrect: The iron center binds to one acetyl carbon and two carbonyl carbons, resulting in 3 Fe-C bonds instead of 2.
(D) is incorrect: The prefix "-N,O" specifies that EDTA acts as a bidentate ligand here, forming only 1 chelate ring instead of 5.
