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Chemistry - Coordination Chemistry Question with Solution | TestHub

ChemistryCoordination ChemistryMiscellaneous/MixedMedium2 minQB
ChemistryMediummultiple choice

For each of the following coordination compounds, state whether the given description about its magnetic nature and type of isomerism is correct.

Select the correct option(s).

Options:(select one or more)

Answer:
A, B, C
Solution:

A. [Cr(NH₃)₄Cl₂]Cl: Cr³⁺ () is paramagnetic. Square planar or octahedral complexes with two identical ligands can exhibit cis-trans isomerism. This is an octahedral complex. Correct.

B. [Ti(H₂O)₅Cl]NO₃: Ti³⁺ () is paramagnetic. Ionisation isomerism involves exchange of an ion inside and outside the coordination sphere. Correct.

C. [Pt(en)(NH₃)Cl]NO₃: Pt²⁺ () in square planar complexes is diamagnetic. Ionisation isomerism is possible. Correct.

D. [Co(NH₃)₄(NO₃)₂]NO₃: Co³⁺ () is diamagnetic (low spin). Exhibits cis-trans isomerism. Incorrect.

Stream:JEESubject:ChemistryTopic:Coordination ChemistrySubtopic:Miscellaneous/Mixed
2mℹ️ Source: QB

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