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Chemistry - Coordination Chemistry Question with Solution | TestHub

ChemistryCoordination ChemistryVBT,CFT(complex compound)Medium2 minPYQ_2021
ChemistryMediummultiple choice

The pair(s) of complexes wherein both exhibit tetrahedral geometry is(are)
(Note:py=pyridine Given: Atomic numbers ofFe, Co, NiandCuare26, 27, 28and29, respectively)

Options:(select one or more)

Answer:
A, B, D
Solution:

FeCl4-sp3 Tetrahedral

FeCO42- : sp3 Tetrahedral (Isoelectronic to NiCO4)

CoCO4- : sp3 Tetrahedral (Isoelectronic to NiCO4)

CoCl42- : sp3 Tetrahedral

NiCo4 : sp3 Tetrahedral (Complex of Mond's process)

NiCN42- : dsp2 square planar (Cyanide is strong field ligand)

CuPy4+ : sp3 Tetrahedral

CuCN43- : sp3 Tetrahedral

Subject:ChemistryTopic:Coordination ChemistrySubtopic:VBT,CFT(complex compound)
2mℹ️ Source: PYQ_2021

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