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Chemistry - Complete d-block Question with Solution | TestHub

ChemistryComplete d-blockd-blockMedium2 minPYQ_2023
ChemistryMediumnumerical

When Fe0.93O is heated in presence of oxygen, it converts to Fe2O3. The number of correct statement/s from the following is ______ .

A. The equivalent weight of Fe0.93O is  Molecular weight0.79

B. The number of moles of Fe2+ and Fe3+ in 1 mole of Fe0.93O is 0.79 and 0.14 respectively.

C. Fe0.93O is metal deficient with lattice comprising of cubic closed packed arrangement of O2- ions.

D. The % composition of Fe2+ and Fe3+ in Fe0.93O is 85% and 15% respectively.

 

Answer:
4.00
Solution:

A:Fe0.93OFe2O3

The valence factor of Fe0.93Onf=3-20093×0.93

nf=0.79

Hence, the equivalent weight =Molecular weight0.79

B:2x+0.93-x×3=2

x=0.79

Fe2+=0.79,Fe3+=0.14

C: In Fe0.93OO2- ions forms the lattice and iron ions occupies the voids in the lattice. As sufficient number of irons are not available, this metal oxide is said to be metal difficient.

D: %Fe2+=0.790.93×100=85%;Fe3+=15%

Stream:JEESubject:ChemistryTopic:Complete d-blockSubtopic:d-block
2mℹ️ Source: PYQ_2023

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