Chemistry - Chemical Kinetics Question with Solution | TestHub

ChemistryChemical KineticsFirst Order ReactionsMedium2 minQB
ChemistryMediummatching list

Assume that the reaction considered here homogeneous gaseous reaction :

List - I

(Containing order of the reaction)

List - II

(Containing properties of the reaction)

(P) Order less than 1

(A) Reaction will not undergo 100% completion in finite time interval

(Q) Order equal to zero

(B) Rate of reaction will remain uniform as long as reactant is remaining

(R) Order greater than or equal to 1

(C) Rate of reaction may increase as the reaction proceeds

 

(D) Reaction can never be elementary

Options:

Answer:
A
Solution:

Question Explanation: Find match the column

Concept: This question is based on first order reaction.

Solution:

 

Zero order: rate = constant = , independent of concentration completes in finite time.

Order (first, second, ...): concentration approaches zero asymptotically, so 100% completion is never achieved in finite time.

Order (fractional or negative): rate can increase as concentration decreases (especially for negative order reactions).

Matching:

P: Order less than 1

Rate may increase as the reaction proceeds (C)

Q: Order equal to zero

Rate remains uniform as long as reactant is present (B)

R: Order greater than or equal to 1

Reaction will not undergo 100% completion in finite time (A)

Final Answer: Option (A)

Stream:JEESubject:ChemistryTopic:Chemical KineticsSubtopic:First Order Reactions
2mℹ️ Source: QB

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