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Chemistry - Chemical Kinetics Question with Solution | TestHub

ChemistryChemical KineticsFirst Order ReactionsHard2 minPYQ_2022
ChemistryHardnumerical

A flask is filled with equal moles ofAandB. The half lives ofAandBare100 sand50 srespectively and are independent of the initial concentration. The time required for the concentration ofAto be four times that ofBis____s.
(Given :ln2=0.693)

Answer:
200.00
Solution:

For first order reaction

k=0.693t12

A=4B

A0e-kAt=4B0e-kBt

as A0=B0;e-kAt=4e-kBt

-kAt=ln4-kBt

 tkB-kA=2ln2

t=2×0.6930.69350-0.693100=2×1002-1=200sec

Stream:JEESubject:ChemistryTopic:Chemical KineticsSubtopic:First Order Reactions
2mℹ️ Source: PYQ_2022

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