Chemistry - Chemical Kinetics Question with Solution | TestHub

ChemistryChemical KineticsMiscellaneous/MixedEasy2 minPYQ_2020
ChemistryEasysingle choice

For the reaction
5  Br – aq  +  BrO 3 − aq  + 6  H + aq →3  Br 2 aq  + 3  H 2 O  l
the rate expression was found to be
–dBrO3–dt   = k Br– H+2 BrO3- 
Which of the following statements is /are correct?
I. Doubling the initial concentration of all the reactants will increase the reaction rate by a factor of 8.
II. Unit of rate constant of the reaction in a buffer solution ismin–1
III. Doubling the concentration of all the reactants at the same time will increase the reaction rate by a factor of 16
IV. rate of conversion of BrO 3 − and rate of disappearance ofBr–are the same

Options:

Answer:
D
Solution:

r=– d BrO 3 − dt    =  1 3 d Br 2 dt
r=KBr- H+2BrO3-
r′=K2Br-2H+22BrO3-=16r

Stream:NTA_ABHYASSubject:ChemistryTopic:Chemical KineticsSubtopic:Miscellaneous/Mixed
⏱ 2mℹ️ Source: PYQ_2020

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