Chemistry - CHEMICAL BONDING Question with Solution | TestHub
Let be the sum of the number of shared O atoms per tetrahedron and the charge on one tetrahedral unit in pyroxene; be the number of elements through Ne larger than H⁻, excluding inert gases; and the number of X-O-X linkages in sodium hexametaphosphate. Find .
Answer:
Solution:
A pyroxene repeat is [SiO₃]²⁻, with two shared oxygens per tetrahedron, giving x=2+(-2)=0 using signed charge. In the radius set intended by the question, none of the non-noble elements through Ne exceeds the radius of H⁻, so y=0. Hexametaphosphate has six P-O-P bridges in its ring, giving z=6. Therefore (x+y+z)/2=3. The mixed atom/ion radius comparison is convention-dependent; this states the set assumed by the printed key.
