Chemistry - Carboxylic acid and their Derivatives Question with Solution | TestHub

ChemistryCarboxylic acid and their DerivativesMiscellaneous/MixedHard2 minQB
ChemistryHardsingle choice

 

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What is the structure of A ?

Options:

Answer:
A
Solution:

The last product is 1-hydroxycyclopentanecarbonitrile, so D is cyclopentanone. Dimethyl adipate A undergoes intramolecular Claisen (Dieckmann) condensation to a five-membered beta-keto ester B, then hydrolysis gives beta-keto acid C and heating decarboxylates to D. HCN adds to D. The ethyl succinate alternatives give the wrong ring size/ester alcohol. Thus A.

Stream:JEESubject:ChemistryTopic:Carboxylic acid and their DerivativesSubtopic:Miscellaneous/Mixed
⏱ 2mℹ️ Source: QB

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