Chemistry - ALCOHOL & ETHER Question with Solution | TestHub

ChemistryALCOHOL & ETHERMiscellaneous/MixedEasy2 minPYQ_2020
ChemistryEasynumerical

How many of the following ethers CANNOT be prepared by Williamson's synthesis?CH3OCH2CH3,C6H5OCH3,(C6H5)2O,(CH3)3COCH3,(C2H5)2O,(CH3)3C-O-C(CH3)3

Answer:
2.00
Solution:

In Williamson's synthesis,
i.1°alkyl halide and3°alkoxide give best yield of corresponding ethers.
ii. In case of,3°alkyl halide, elimination competes over substitution and alkene is obtained as a product.
iii. Aryl halides do not undergo nucleophilic substitution unless it is activated by the presence of electron withdrawing group. Thus,(C6H5)2Oand(CH3)3C-O-C(CH3)3cannot be prepared by Williamson's synthesis.

Stream:NTA_ABHYASSubject:ChemistryTopic:ALCOHOL & ETHERSubtopic:Miscellaneous/Mixed
2mℹ️ Source: PYQ_2020

Doubts & Discussion

Loading discussions...