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Chemistry - Thermodynamics - II Question with Solution | TestHub

ChemistryThermodynamics - IIFree Energy and EquilibriumHard2 minPYQ_2022
ChemistryHardnumerical

The standard free energy change ΔG° for 50% dissociation of N2O4 into NO2 at 27 °C and 1 atm pressure is -x J mol-1. The value of x is -..... J. (Nearest Integer)

[Given : R=8.31 J K-1 mol-1, log1.33=0.1239  ln10=2.3]

Answer:
710.00
Solution:

N2O4g2NO2g

1-α           2α

Kp=4α2p1-α2=4×0.52×11-0.52=10.75

Kp=43

ΔGo=-2.303 RT log Kp

=-2.3×8.31×300 log 43=-2.3×8.31×300 ×0.1239

=-710 J

Stream:JEESubject:ChemistryTopic:Thermodynamics - IISubtopic:Free Energy and Equilibrium
2mℹ️ Source: PYQ_2022

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