For a reaction, A ⇌ P , the plots of A a n d P with time at temperatures T 1 a n d T 2 are given below. If T 2 T 1 , the correct statement(s) is (are) (Assume ∆ H ⊝ a n d ∆ S ⊝ are independent of te

Question

For a reaction, A ⇌ P , the plots of A a n d P with time at temperatures T 1 a n d T 2 are given below. If T 2 > T 1 , the correct statement(s) is (are) (Assume ∆ H ⊝ a n d ∆ S ⊝ are independent of temperature and ratio of ln K a t T 1 t o ln K a t T 2 is greater than T 2 / T 1 . Here H, S , G and K are enthalpy, entropy, Gibbs energy and equilibrium constant, respectively.)

TestHub · Accepted Answer

A ⇌ P Given T 2 > T 1 ln ⁡ K 1 ln ⁡ K 2 > T 2 T 1 ⇒ T 1 ​ ln K 1 ​ > T 2 ​ ln K 2 ​ ⇒ - ∆ G 1 0 > - ∆ G 2 0 ⇒ - ∆ H 0 + T 1 ∆ S 0 > - ∆ H 0 + T 2 ∆ S o ⇒ T 1 ∆ S 0 > T 2 ∆ S 0 ⇒ ∆ S o < 0 At T 2 temperature concentration of product is decreases that shows reaction is exothermic.

Chemistry - Thermodynamics - II Question with Solution | TestHub

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