Chemistry - Thermodynamics - I Question with Solution | TestHub

ChemistryThermodynamics - IAdiabatic Process/PolytropicHard2 minQB
ChemistryHardsingle choice

A mixture of 1 mol He and 1 mol H2 (ideal, vibrations not excited) at pressure P and volume V is isothermally compressed to V/16, giving pressure Pi. Starting from the same initial state it is instead compressed reversibly and adiabatically to V/16, giving pressure Pa. The ratio Pa/Pi is

Options:

Answer:
C
Solution:

For the mixture Cv = 3/2R + 5/2R = 4R and Cp = 6R (per 2 mol), so γmix = 1.5. Isothermal: Pi = 16P. Adiabatic: Pa = 161.5P = 64P. Pa/Pi = 160.5 = 4. (Averaging the two γ values gives 4.4, which is wrong.) Matches (c).

Stream:JEESubject:ChemistryTopic:Thermodynamics - ISubtopic:Adiabatic Process/Polytropic
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