Chemistry - STRUCTURAL ISOMERISM Question with Solution | TestHub

ChemistrySTRUCTURAL ISOMERISMTAUTOMERISMMedium2 minQB
ChemistryMediumsingle choice
Passage / Comprehension

Keto-enol tautomerism is a dynamic equilibrium which depends on the stability of keto or enol Tautomerism take place in dilute acidic or basic medium.

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How many hydrogen atoms replaced by deuterium ?

Options:

Answer:
B
Solution:

Question Explanation:

The question asks for the final product formed when 2-Methylcyclopentanone is treated extensively with

heavy water (D2O) in a basic medium (DO- ).

Concept: This question is based on tautomerism and H-D exchange.

Solution:

In the presence of a base, the acidic alpha-hydrogens of the ketone undergo keto-enol tautomerism.

During this process, all available alpha-hydrogens are sequentially replaced by deuterium atoms from the solvent.

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Stream:JEESubject:ChemistryTopic:STRUCTURAL ISOMERISMSubtopic:TAUTOMERISM
2mℹ️ Source: QB

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