Chemistry - Stoichiometry Question with Solution | TestHub
Chile saltpeter, a source of NaNO₃, also contains NaIO₃. The NaIO₃ can be used as a source of iodine, produced in the following reactions: IO₃⁻ + 3HSO₃⁻ I⁻ + 3H⁺ + 3SO₄²⁻ and 5I⁻ + IO₃⁻ + 6H⁺ 3I₂ + 3H₂O. One litre of Chile saltpeter solution containing 5.94 g NaIO₃ is treated with stoichiometric quantity of NaHSO₃. Now an additional amount of same solution is added to the reaction mixture to bring about the second reaction. (I = 127)
What additional volume of Chile saltpeter must be added in step II to bring in complete conversion of I⁻ to I₂?
Options:
Answer:
Solution:
Step I produces 0.03 mol I⁻. Step II needs 1 mol IO₃⁻ per 5 mol I⁻, so IO₃⁻ = 0.006 mol. Volume = 0.006/0.03 × 1000 = 200 ml, matching (b).
